Advances in Heterocyclic Chemistry, Vol. 13 by A. R. & Boulton, A. J. [Eds]. Katritzky

By A. R. & Boulton, A. J. [Eds]. Katritzky

(from preface)Volume thirteen of this serial e-book contains six chapters of which 4 care for basic bills of compound sessions: 1-azirines (F. W. Fowler), phenanthridincs (B. R. T. Keene and P. Tissington), tri-thiapentalenes (N. Lozac'h), and heterocyclic fcrrocenes (F. D. Popp and E. B. Moynahan). the opposite chapters are fascinated about specific features of the chemistry of teams of heterocycles: the tautomerism of purines (B. Pullman and A. Pullman) and quantitative features of the electrophilic substitution reactions of five-membercd jewelry (G. Marino).

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676, 76 (1964). 154 A . N . Nesmeyanov, I. B. Zlotina, N. E. Kolobova, arid K. N. Anisimov, Izv. Akad. Nauk SSSR, Ser. Khim. 2127 (1968); Chem. Abstr. 70, 29030r 152 153 ( 1969). 155 E. Fischer and K. Plesske, Chem. Ber. 92, 2841 (1959). P. D. POPP AND E. B. MOYNAHAN 42 [See. IV. Cyclopentadienylmanganese tricarbonylcarboxylic acid chloride has been reacted with quinoline and hydrogen cyanide t o give the Reissert compound (203). " Analogous compounds have also been prepared from 2-methyl- and 3-methylcyclopentadienylmanganese tricarbonylcarboxylic acid chloride.

Khim. 335 (1966); Chem. Abstr. 64,17634 (1966). 111 L. Hennig, arid I. P. Sereda, J . P r a k t . Chem. 32, 105 (1966). 112 R . Dabard and B. Gauthoron, C . R. Acad. Sci. 254,2014 (1962). 113 J. Tirouflet, R. Dabard, and E. Laviron, Bull. SOC. Chim. Fr. 1655 (1963). 114 H. Krasa, and K. Schlogl, Monatsh. Chem. 100, 1552 (1969). 110 F. D. POPP A N D E. B. M O Y N A H A N 26 [Sec. A. 116 Only the endo isomers were formed. A number of additional nitrogen- R' e 115 116 (122) D. Heydenhauss and H. Schubert, 2.

62,59 (1962). See. ] 31 HETEROCYCLIC FERROCENES Whether or not chelates can be considered as true cyclic compounds is open to question, but the formation of 141,lZ4142,lZ5and 143lZ6 might be noted. e Fe (142) M = Fe, n = 3 M = CU, n = 2 e NHR I Fe I -CH=N S \CC GH=N Fe C. ggA number of cyclic lactones have been reported. Thus, reduction of P-ferrocenoylpropionic acid with sodium borohydride gave the butyrolactone ( 145)lZ7* lZ8 which was smoothly hydrogenated to y-ferrocenylbutyric 124 D. W. Slocum, T.

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