Calixarenes in the Nanoworld by David Gutsche (auth.), Jacques Vicens, Jack Harrowfield,

By David Gutsche (auth.), Jacques Vicens, Jack Harrowfield, Lassaad Baklouti (eds.)

Calixarenes were generally exploited in all components of supramolecular chemistry over the last 3 a long time and lots of contemporary advancements have involved their functions within the construction of chemical entities with the size of nanometres, as in "nanochemistry".

Calixarenes within the Nanoworld

  • Relates calixarenes to nanochemistry – key info for industries engaged within the creation of high-tech materials.
  • Provides a well timed assessment of either what's recognized and the interesting customers supplied through calixarenes
  • Contains a number of evaluation articles which outline the significance of calixarenes as reagents in nanochemistry.

Calixarenes within the Nanoworld should be valuable to scholars, teachers, learn associations, and industries engaged within the creation of high-tech materials.

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Böhmer, unpublished. 50. O. Molokanova, M. O. Vysotsky, Y. Cao, I. Thondorf and V. Böhmer, unpublished. 51. A. X. Wu, L. Isaacs, J. Am. Chem. Soc. 125, 4831-4835 (2003); P. Mukhopadhyay, A. X. Wu, L. Isaacs, J. Org. Chem. 69, 6157-6164 (2005). 52. Y. Rudzevich, V. Rudzevich, D. Schollmeyer, I. Thondorf and V. Böhmer, Chem. Lett. 7, 613-616 (2005). 53. Y. Rudzevich, V. Rudzevich, C. Moon, I. Schnell, K. Fischer and V. Böhmer, J. Am. Chem. Soc. 127, 14168-14169 (2005). Chapter 3 CALIX-ROTAXANES AND -CATENANES Interlocking with cavities Zhan-Ting Li, Xin Zhao, and Xue-Bin Shao State Key Laboratory of Bioorganic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, China.

Soc. 127, 12697-12708 (2005). 46 Chapter 2 36. R. H. Grubbs, Tetrahedron 60, 7117-7140 (2004); T. M. Trnka and R. H. Grubbs, Acc. Chem. Res. 34, 18-29 (2001). 37. M. O. Vysotsky, M. Bolte, I. Thondorf and V. Böhmer, Chem. Eur. J. 9, 3375-3382 (2003). 38. M. Saadioui, A. Shivaniuk, V. Böhmer and W. Vogt, J. Org. Chem. 64, 3774-3777 (1999). 39. A. Bogdan, M. O. Vysotsky, T. Ikai, Y. Okamoto and V. Böhmer, Chem. Eur. J. 10, 33243330 (2004). 40. M. Bolte, A. Bogdan, M. O. Vysotsky and V. Böhmer, unpublished.

2. Tetraurea Calix[4]arenes 37 The data presented in Figs. 14 and 15 show that the unusual cone conformation of a tetramethylether is fixed by the loops, which are too short to allow the molecule to assume the partial cone conformation usually preferred by tetramethyl ethers of calix[4]arenes. 45 Figure 2-15. Single crystal X-ray structure of 15 (n = 10) showing the molecule in a “pinched” cone conformation. 5 Huge Macrocycles The template synthesis described above for tetraloop compounds can be extended if, in a further step, the urea links to the calix[4]arene can be cleaved.

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