By Amelia Pilar Rauter, Thisbe Lindhorst, Yves Queneau, M. Philippe, Jacques Auge, Valerie Molinier, Mattieu Sauthier, Yves Chapleur, Jean-Marie Beau, Qian Wan, Marie-Christine Scherrmann, Richard Daniellou, Jose Kovensky, Slawomir Jarosz, Jean-Maurice Malle
Volume forty of Carbohydrate Chemistry: Chemical and organic methods demonstrates the significance of the glycosciences for innovation and societal development. Carbohydrates are molecules with crucial roles in biology and in addition function renewable assets for the iteration of recent chemical substances and fabrics. Honouring Professor André Lubineau’s reminiscence, this quantity resembles a different selection of contributions within the fields of eco-friendly and low-carbon chemistry, leading edge artificial method and layout of carbohydrate architectures for medicinal and organic chemistry.
Green technique is illustrated by way of money owed at the commercial improvement of water-promoted reactions (C-glycosylation, cycloadditions) and the layout of eco-friendly approaches and synthons in the direction of sugar-based surfactants and fabrics. The in particular tough alterations on the anomeric middle are provided in different contributions on glycosylation methodologies utilizing iron or gold catalysis, electrochemical or enzymatic (thio)glycosylation, exo-glycal chemistry and bioengineering of carbohydrate synthases. Then, synthesis and constitution of multivalent and supramolecular oligosaccharide architectures are mentioned and on the topic of their actual homes and alertness power, e.g. for deepening our figuring out of organic approaches, reminiscent of enzymatic pathways or bacterial adhesion, and layout of antibacterial, antifungal and cutting edge anticancer vaccines or drugs.
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